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Nigeria’s coastal regions, including Ondo State, experience severe electricity deficits due to unreliable grid infrastructure and dependence on fossil fuels. This study investigates the adoption of hydrogen (H₂) fuel cell technology as a clean and scalable alternative for power generation in these areas. Using simulations developed in Python and MATLAB, hydrogen fuel cell performance was modeled under varying flow rates (25–50 L/h) and environmental conditions. Results show a linear increase in power output (13.9–27.9 kW) with stable conversion efficiency (approximately 60%), indicating reliability and scalability for rural and industrial applications. Comparative analysis suggests hydrogen fuel cells can reduce greenhouse gas emissions, operational costs, and environmental degradation compared to diesel-powered systems. Techno-economic and policy assessments highlight long-term cost savings, energy security, and social benefits when integrated with solar-powered hydrogen production. The study concludes that hydrogen fuel cells offer a viable, sustainable pathway for clean electricity generation and energy transition in Ondo State’s coastal regions.